Publications

27. Mechanistic investigations on a homogeneous ruthenium Guerbet catalyst in a flow reactor
Nicholas M. Wang, Sam Dillon and Damien Guironnet
Royal Society of Chemistry 2021 DOI: 10.1039/d1re00551k
Publication TOC

26. Implicit Side-Chain Model and Experimental Characterization of Bottlebrush Block Copolymer Solution Assembly                                            Tianyuan Pan, Bijal B. Patel, Dylan J. Walsh, Sarit Dutta, Damien Guironnet, Ying Diao, and Charles E. Sing
Macromolecules 2021 DOI: 10.1021/acs.macromol.1c00336

 

25. PolyChemPrint: A hardware and software framework for benchtop additive manufacturing of functional polymeric materials
Bijal B. Patel, Yilong Chang, Sang Kyu Park, Siqing Wang, John Rosheck, Kush Patel, Dylan Walsh, Damien Guironnet, and Ying Diao
Journal of Polymer Science 2021 DOI: 10.1002/pol.20210086
Publication TOC

24. Synthesis of telechelic polyolefins
Tianwei Yan and Damien Guironnet
Polymer Chemistry 2021 DOI: 10.1039/D1PY00819F
Publication TOC

23. Photophysical properties of soluble light-harvesting polyhydrofurans from post-polymerization functionalization of polyketones
Maggie Potter and Damien Guironnet
European Polymer Journal 2021 DOI: 10.1016/j.eurpolymj.2021.110302
Publication TOC

22. Challenges of Size-Exclusion Chromatography for the Analysis of Bottlebrush Polymers
Dylan J. Walsh, Matthew A. Wade, Simon A. Rogers and Damien Guironnet
Macromolecules 2020 DOI: 10.1021/acs.macromol.0c01357
Publication TOC

21. Ring-Opening Polymerization of Cyclic Esters in an Aqueous Dispersion
Danielle Harrier, Paul Kenis and Damien Guironnet
Macromolecules 2020 DOI: 10.1021/acs.macromol.0c01300E
Publication TOC

20. Amphiphilic triblock copolymers containing polypropylene as the middle block
Tianwei Yan and Damien Guironnet
Angewandte Chemie 2020 DOI: 10.1002/anie.202009165
Publication TOC

19. General route to design polymer molecular weight distributions through flow chemistry
Dylan J. Walsh, Devin A. Schinski, Robert A. Schneider and Damien Guironnet
Nature Communications 2020 DOI: 10.1038/s41467-020-16874-6
Publication TOC

18. Tunable structural color of bottlebrush block copolymers through direct-write 3D printing from solution
Bijal B. Patel, Dylan J. Walsh, Do Hoon Kim, Justin Kwok, Byeongdu Lee, Damien Guironnet and Ying Diao
Science Advances 2020 DOI: 10.1126/sciadv.aaz7202
Publication TOC

17. Biphasic Seeded Emul sion Polymerization in a Tubular Flow Reactor
Alexander G. Horn, Thomas C. Johnston and Damien Guironnet
Industrial & Engineering Chemistry Research 2020 DOI: 10.1021/acs.iecr.0c00961
Publication TOC

16. Color, structure, and rheology of a diblock bottlebrush copolymer solution
Matthew A. Wade, Dylan Walsh, Johnny Ching-Wei Lee, Elizabeth Kelley, Katie Weigandt, Damien Guironnet
and Simon A. Rodgers
Soft Matter 2020 DOI: 10.1021/acs.iecr.0c00961
Publication TOC

15. Polyethylene Containing Triblock Copolymers Synthesized by Post-polymerization Functionalization
Tianwei Yan and Damien Guironnet
Macromolecules 2020 DOI: 10.1021/acs.macromol.0c00627
Publication TOC

14. Tandem Catalysts for Polyethlene Upcycling: a Simple Kinetic Model
Damien Guironnet and Baron Peters
Journal of Physical Chemistry A 2020 DOI: 10.1021/acs.jpca.0c01363
Publication TOC

13. Combination of olefin insertion polymerization and olefin metathesis to extend the topology and composition of polyolefins
Tianwei Yan and Damien Guironnet
SCIENCE CHINA Chemistry 2020 DOI: 10.1007/s11426-020-9724-9
Publication TOC

12. Recent Trends in Catalytic Polymerizations
Dylan J. Walsh, Michael G. Hyatt, Susannah A. Miller and Damien Guironnet
ACS Catalysis 2019 DOI: 10.1021/acscatal.9b03226
Publication TOC

11. Mechanistic and Kinetic Studies of the Ring Opening Metathesis Polymerization of Norbornenyl Monomers by a Grubbs Third Generation Catalyst
Michael G. Hyatt, Dylan J. Walsh, Richard L. Lord, José G. Andino Martinez and Damien Guironnet
J. Am. Chem. Soc. 2019 DOI: 10.1021/jacs.9b09752
Publication TOC

10. Engineering of Molecular Geometry in Bottlebrush Polymers
Dylan J. Walsh, Sarit Dutta, Charles E. Sing and Damien Guironnet
Macromolecules 2019 DOI: 10.1021/acs.macromol.9b00845
Publication TOC

9. Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants
Camille Boucher-Jacobs, Bo Li, Charles M. Schroeder and Damien Guironnet
Polymer Chemistry 2019 DOI: 10.1039/C9PY00154A
Publication TOC

8. Introduction of Highly Tunable End-Groups in Polyethylene via Chain-Transfer Polymerization using a Cobalt(III) Catalyst
Michael Hyatt and Damien Guironnet
Organometallics 2019 DOI: 10.1021/acs.organomet.8b00765
Publication TOC

7. Dilute solution structure of bottlebrush polymers
Sarit Dutta, Matthew A Wade, Dylan J Walsh, Damien Guironnet,, Simon A Rogers and Charles E Sing
Soft Matter 2019 DOI: 10.1039/C9SM00033J

Publication TOC

6. Macromolecules with programmable shape, size and chemistry
Dylan J. Walsh and Damien Guironnet
Proceedings of the National Academy of Sciences 2019 DOI: 10.1073/pnas.1817745116
Publication TOC

5. One-Pot Synthesis of Block Copolymers Containing a Polyolefin Block
Tianwei Yan, Dylan J. Walsh, Chengling Qiu and Damien Guironnet
Macromolecules 2018 DOI: 10.1021/acs.macromol.8b02475
Publication TOC

4. Catalytic Synthesis of Functionalized (polar and non-polar) Polyolefin Block Copolymers
Dylan J. Walsh, Eric Su and Damien Guironnet
Chem. Sci 2018, 9, 4703 DOI: 10.1039/C8SC00450A
Publication TOC

3. Encapsulation of Catalyst in Block Copolymer Micelles for the Polymerization of Ethylene in Aqueous Medium
Camille Boucher-Jacobs, Muhammad Rabnawaz, Joshua S. Katz, Ralph Even and Damien Guironnet
Nature Communications 9, 841 DOI: 10.1038/s41467-018-03253-5
Publication TOC

2. Kinetic Study of Living Ring-Opening Metathesis Polymerization with Third-Generation Grubbs Catalysts
Dylan J. Walsh, Sii Hong Lau, Michael G. Hyatt and Damien Guironnet
J. Am. Chem. Soc. 2017, 139, 13644 DOI: 10.1021/jacs.7b08010
Publication TOC

1. Silane as Chain Transfer Agent for the polymerization of Ethylene Catalyzed by a Palladium(II) Diimine Catalyst
Michael G. Hyatt and Damien Guironnet
ACS Catal. 20177, 5717. DOI: 10.1021/acscatal.7b01299
Publication TOC

 

Publications (Prior to UIUC)

 

  1. Synthesis and Characterization of Carbazolide-Based Iridium PNP Pincer Complexes. Mechanistic and Computational Investigation of Alkene Hydrogenation: Evidence for an Ir(III)/Ir(V)/Ir(III) Catalytic Cycle
    Chen Cheng, Bong Gon Kim, Damien Guironnet, Maurice Brookhart, Changjian Guan, David Y. Wang,
    Karsten Krogh-Jespersen and Alan S. Goldman
    J. Am. Chem. Soc. 2014136, 6672. DOI: 10.1021/ja501572g
  2. Synthesis of p-Xylene from Ethylene
    Thomas W. Lyons, Damien Guironnet, Michael Findlater and Maurice Brookhart
    J. Am. Chem. Soc. 2012134, 15708. DOI: 10.1021/ja307612b
  3. Preparation and Characterization of Conjugated Polymers Made by Postpolymerization Reactions of Alternating Polyketones
    Chen Cheng, Damien Guironnet, James Barborak and Maurice Brookhart
    J. Am. Chem. Soc. 2011133, 9658. DOI: 10.1021/ja202361k
  4. Reactivity of Methacrylates in Insertion Polymerization
    Thomas Rünzi, Damien Guironnet, Inigo Göttker-Schnetmann and Stefan Mecking
    J. Am. Chem. Soc. 2010132, 16623. DOI: 10.1021/ja107538r
  5. Mechanistic Insights on Acrylate Insertion Polymerization
    Damien Guironnet, Lucia Caporaso, Boris Neuwald, Inigo Göttker-Schnetmann, Luigi Cavallo and Stefan Mecking
    J. Am. Chem. Soc. 2010132, 4418. DOI: 10.1021/ja910760n
  6. Water-Soluble Complexes [(k2P,O-Phosphinesulfonato)PdMe(L)] and Their Catalytic Properties
    Dao Zhang, Damien Guironnet, Inigo Göttker-Schnetmann and Stefan Mecking
    Organometallics 200928, 4072. DOI: 10.1021/om9003225
  7. Ethylene Polymerization in Supercritical Carbon Dioxide with Binuclear Nickel(ii) Catalysts
    Damien Guironnet, Tobias Friedberger and Stefan Mecking
    Dalton Trans. 2009, 8929. DOI: 10.1039/B912883B
  8. Catalytic Polymerization in Dense CO2 to Controlled Microstructure Polyethylenes
    Damien Guironnet, Inigo Göttker-Schnetmann and Stefan Mecking
    Macromolecules 200942, 8157. DOI: 10.1021/ma901397q
  9. Insertion Polymerization of Acrylate
    Damien Guironnet, Philipp Roesle, Thomas Rünzi, Inigo Göttker-Schnetmann and Stefan Mecking
    J. Am. Chem. Soc. 2008131, 422. DOI: 10.1021/ja808017n
  10. Control of Molecular Weight in Ni(ii)-Catalyzed Polymerization via the Reaction Medium
    Damien Guironnet, Thomas Rünzi, Inigo Göttker-Schnetmann and Stefan Mecking
    Chem. Commun. 2008, 4965. DOI: 10.1039/B811888D

 

Patents 

 
  1. Encapsulated catalyst and methods of olefin polymerization
    Damien Guironnet Muhammad Rabanawaz, Ralph Even, Andrew Hughes and Joshua Katz
    Rohm and Haas Company and The Board Of Trustees Of The University of Illinois, USA. 2021, 27pp.
    Patent Number: US10947330
  2. Flow controlled synthesis of bottlebrush macromolecules
    Damien Guironnet and Dylan J. Walsh
    The Board Of Trustees Of The University of Illinois, USA. 2020, 73pp. Patent Number: US20200407488A1
  3. Method for synthesis of end-functionalized polyolefins
    Damien Guironnet Michael G. Hyatt and Dylan J. Walsh
    The Board Of Trustees Of The University of Illinois, USA. 2019, 17pp. Patent Number: US10414903B2
  4. Methods for synthesis of polyolefin-containing block copolymers
    Damien Guironnet and Dylan J. Walsh
    The Board Of Trustees Of The University of Illinois, USA. 2019, 24pp. Patent Number: US10370521B2
  5. Multistep catalytic synthesis of p-xylene and toluene
    Maurice Brookhart, Michael Findlater, Damien Guironnet and Thomas W. Lyons
    The University of North Carolina At Chapel Hill, USA. 2013, 12pp. Patent Number: US20130237732A1

 

Publications

27. Mechanistic investigations on a homogeneous ruthenium Guerbet catalyst in a flow reactor
Nicholas M. Wang, Sam Dillon and Damien Guironnet
Royal Society of Chemistry 2021 DOI: 10.1039/d1re00551k
Publication TOC

26. Implicit Side-Chain Model and Experimental Characterization of Bottlebrush Block Copolymer Solution Assembly                                            Tianyuan Pan, Bijal B. Patel, Dylan J. Walsh, Sarit Dutta, Damien Guironnet, Ying Diao, and Charles E. Sing
Macromolecules 2021 DOI: 10.1021/acs.macromol.1c00336

 

25. PolyChemPrint: A hardware and software framework for benchtop additive manufacturing of functional polymeric materials
Bijal B. Patel, Yilong Chang, Sang Kyu Park, Siqing Wang, John Rosheck, Kush Patel, Dylan Walsh, Damien Guironnet, and Ying Diao
Journal of Polymer Science 2021 DOI: 10.1002/pol.20210086
Publication TOC

24. Synthesis of telechelic polyolefins
Tianwei Yan and Damien Guironnet
Polymer Chemistry 2021 DOI: 10.1039/D1PY00819F
Publication TOC

23. Photophysical properties of soluble light-harvesting polyhydrofurans from post-polymerization functionalization of polyketones
Maggie Potter and Damien Guironnet
European Polymer Journal 2021 DOI: 10.1016/j.eurpolymj.2021.110302
Publication TOC

22. Challenges of Size-Exclusion Chromatography for the Analysis of Bottlebrush Polymers
Dylan J. Walsh, Matthew A. Wade, Simon A. Rogers and Damien Guironnet
Macromolecules 2020 DOI: 10.1021/acs.macromol.0c01357
Publication TOC

21. Ring-Opening Polymerization of Cyclic Esters in an Aqueous Dispersion
Danielle Harrier, Paul Kenis and Damien Guironnet
Macromolecules 2020 DOI: 10.1021/acs.macromol.0c01300E
Publication TOC

20. Amphiphilic triblock copolymers containing polypropylene as the middle block
Tianwei Yan and Damien Guironnet
Angewandte Chemie 2020 DOI: 10.1002/anie.202009165
Publication TOC

19. General route to design polymer molecular weight distributions through flow chemistry
Dylan J. Walsh, Devin A. Schinski, Robert A. Schneider and Damien Guironnet
Nature Communications 2020 DOI: 10.1038/s41467-020-16874-6
Publication TOC

18. Tunable structural color of bottlebrush block copolymers through direct-write 3D printing from solution
Bijal B. Patel, Dylan J. Walsh, Do Hoon Kim, Justin Kwok, Byeongdu Lee, Damien Guironnet and Ying Diao
Science Advances 2020 DOI: 10.1126/sciadv.aaz7202
Publication TOC

17. Biphasic Seeded Emul sion Polymerization in a Tubular Flow Reactor
Alexander G. Horn, Thomas C. Johnston and Damien Guironnet
Industrial & Engineering Chemistry Research 2020 DOI: 10.1021/acs.iecr.0c00961
Publication TOC

16. Color, structure, and rheology of a diblock bottlebrush copolymer solution
Matthew A. Wade, Dylan Walsh, Johnny Ching-Wei Lee, Elizabeth Kelley, Katie Weigandt, Damien Guironnet
and Simon A. Rodgers
Soft Matter 2020 DOI: 10.1021/acs.iecr.0c00961
Publication TOC

15. Polyethylene Containing Triblock Copolymers Synthesized by Post-polymerization Functionalization
Tianwei Yan and Damien Guironnet
Macromolecules 2020 DOI: 10.1021/acs.macromol.0c00627
Publication TOC

14. Tandem Catalysts for Polyethlene Upcycling: a Simple Kinetic Model
Damien Guironnet and Baron Peters
Journal of Physical Chemistry A 2020 DOI: 10.1021/acs.jpca.0c01363
Publication TOC

13. Combination of olefin insertion polymerization and olefin metathesis to extend the topology and composition of polyolefins
Tianwei Yan and Damien Guironnet
SCIENCE CHINA Chemistry 2020 DOI: 10.1007/s11426-020-9724-9
Publication TOC

12. Recent Trends in Catalytic Polymerizations
Dylan J. Walsh, Michael G. Hyatt, Susannah A. Miller and Damien Guironnet
ACS Catalysis 2019 DOI: 10.1021/acscatal.9b03226
Publication TOC

11. Mechanistic and Kinetic Studies of the Ring Opening Metathesis Polymerization of Norbornenyl Monomers by a Grubbs Third Generation Catalyst
Michael G. Hyatt, Dylan J. Walsh, Richard L. Lord, José G. Andino Martinez and Damien Guironnet
J. Am. Chem. Soc. 2019 DOI: 10.1021/jacs.9b09752
Publication TOC

10. Engineering of Molecular Geometry in Bottlebrush Polymers
Dylan J. Walsh, Sarit Dutta, Charles E. Sing and Damien Guironnet
Macromolecules 2019 DOI: 10.1021/acs.macromol.9b00845
Publication TOC

9. Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants
Camille Boucher-Jacobs, Bo Li, Charles M. Schroeder and Damien Guironnet
Polymer Chemistry 2019 DOI: 10.1039/C9PY00154A
Publication TOC

8. Introduction of Highly Tunable End-Groups in Polyethylene via Chain-Transfer Polymerization using a Cobalt(III) Catalyst
Michael Hyatt and Damien Guironnet
Organometallics 2019 DOI: 10.1021/acs.organomet.8b00765
Publication TOC

7. Dilute solution structure of bottlebrush polymers
Sarit Dutta, Matthew A Wade, Dylan J Walsh, Damien Guironnet,, Simon A Rogers and Charles E Sing
Soft Matter 2019 DOI: 10.1039/C9SM00033J

Publication TOC

6. Macromolecules with programmable shape, size and chemistry
Dylan J. Walsh and Damien Guironnet
Proceedings of the National Academy of Sciences 2019 DOI: 10.1073/pnas.1817745116
Publication TOC

5. One-Pot Synthesis of Block Copolymers Containing a Polyolefin Block
Tianwei Yan, Dylan J. Walsh, Chengling Qiu and Damien Guironnet
Macromolecules 2018 DOI: 10.1021/acs.macromol.8b02475
Publication TOC

4. Catalytic Synthesis of Functionalized (polar and non-polar) Polyolefin Block Copolymers
Dylan J. Walsh, Eric Su and Damien Guironnet
Chem. Sci 2018, 9, 4703 DOI: 10.1039/C8SC00450A
Publication TOC

3. Encapsulation of Catalyst in Block Copolymer Micelles for the Polymerization of Ethylene in Aqueous Medium
Camille Boucher-Jacobs, Muhammad Rabnawaz, Joshua S. Katz, Ralph Even and Damien Guironnet
Nature Communications 9, 841 DOI: 10.1038/s41467-018-03253-5
Publication TOC

2. Kinetic Study of Living Ring-Opening Metathesis Polymerization with Third-Generation Grubbs Catalysts
Dylan J. Walsh, Sii Hong Lau, Michael G. Hyatt and Damien Guironnet
J. Am. Chem. Soc. 2017, 139, 13644 DOI: 10.1021/jacs.7b08010
Publication TOC

1. Silane as Chain Transfer Agent for the polymerization of Ethylene Catalyzed by a Palladium(II) Diimine Catalyst
Michael G. Hyatt and Damien Guironnet
ACS Catal. 20177, 5717. DOI: 10.1021/acscatal.7b01299
Publication TOC

 

Publications (Prior to UIUC)

 

  1. Synthesis and Characterization of Carbazolide-Based Iridium PNP Pincer Complexes. Mechanistic and Computational Investigation of Alkene Hydrogenation: Evidence for an Ir(III)/Ir(V)/Ir(III) Catalytic Cycle
    Chen Cheng, Bong Gon Kim, Damien Guironnet, Maurice Brookhart, Changjian Guan, David Y. Wang,
    Karsten Krogh-Jespersen and Alan S. Goldman
    J. Am. Chem. Soc. 2014136, 6672. DOI: 10.1021/ja501572g
  2. Synthesis of p-Xylene from Ethylene
    Thomas W. Lyons, Damien Guironnet, Michael Findlater and Maurice Brookhart
    J. Am. Chem. Soc. 2012134, 15708. DOI: 10.1021/ja307612b
  3. Preparation and Characterization of Conjugated Polymers Made by Postpolymerization Reactions of Alternating Polyketones
    Chen Cheng, Damien Guironnet, James Barborak and Maurice Brookhart
    J. Am. Chem. Soc. 2011133, 9658. DOI: 10.1021/ja202361k
  4. Reactivity of Methacrylates in Insertion Polymerization
    Thomas Rünzi, Damien Guironnet, Inigo Göttker-Schnetmann and Stefan Mecking
    J. Am. Chem. Soc. 2010132, 16623. DOI: 10.1021/ja107538r
  5. Mechanistic Insights on Acrylate Insertion Polymerization
    Damien Guironnet, Lucia Caporaso, Boris Neuwald, Inigo Göttker-Schnetmann, Luigi Cavallo and Stefan Mecking
    J. Am. Chem. Soc. 2010132, 4418. DOI: 10.1021/ja910760n
  6. Water-Soluble Complexes [(k2P,O-Phosphinesulfonato)PdMe(L)] and Their Catalytic Properties
    Dao Zhang, Damien Guironnet, Inigo Göttker-Schnetmann and Stefan Mecking
    Organometallics 200928, 4072. DOI: 10.1021/om9003225
  7. Ethylene Polymerization in Supercritical Carbon Dioxide with Binuclear Nickel(ii) Catalysts
    Damien Guironnet, Tobias Friedberger and Stefan Mecking
    Dalton Trans. 2009, 8929. DOI: 10.1039/B912883B
  8. Catalytic Polymerization in Dense CO2 to Controlled Microstructure Polyethylenes
    Damien Guironnet, Inigo Göttker-Schnetmann and Stefan Mecking
    Macromolecules 200942, 8157. DOI: 10.1021/ma901397q
  9. Insertion Polymerization of Acrylate
    Damien Guironnet, Philipp Roesle, Thomas Rünzi, Inigo Göttker-Schnetmann and Stefan Mecking
    J. Am. Chem. Soc. 2008131, 422. DOI: 10.1021/ja808017n
  10. Control of Molecular Weight in Ni(ii)-Catalyzed Polymerization via the Reaction Medium
    Damien Guironnet, Thomas Rünzi, Inigo Göttker-Schnetmann and Stefan Mecking
    Chem. Commun. 2008, 4965. DOI: 10.1039/B811888D

 

Patents 

 
  1. Encapsulated catalyst and methods of olefin polymerization
    Damien Guironnet Muhammad Rabanawaz, Ralph Even, Andrew Hughes and Joshua Katz
    Rohm and Haas Company and The Board Of Trustees Of The University of Illinois, USA. 2021, 27pp.
    Patent Number: US10947330
  2. Flow controlled synthesis of bottlebrush macromolecules
    Damien Guironnet and Dylan J. Walsh
    The Board Of Trustees Of The University of Illinois, USA. 2020, 73pp. Patent Number: US20200407488A1
  3. Method for synthesis of end-functionalized polyolefins
    Damien Guironnet Michael G. Hyatt and Dylan J. Walsh
    The Board Of Trustees Of The University of Illinois, USA. 2019, 17pp. Patent Number: US10414903B2
  4. Methods for synthesis of polyolefin-containing block copolymers
    Damien Guironnet and Dylan J. Walsh
    The Board Of Trustees Of The University of Illinois, USA. 2019, 24pp. Patent Number: US10370521B2
  5. Multistep catalytic synthesis of p-xylene and toluene
    Maurice Brookhart, Michael Findlater, Damien Guironnet and Thomas W. Lyons
    The University of North Carolina At Chapel Hill, USA. 2013, 12pp. Patent Number: US20130237732A1